Tetrahedron letters

Oxidation of N-methyl-9-t-butylacridane by iodosylbenzene catalyzed by tetrakis (pentafluorophenyl) porphyrin iron (III). A tool to investigate the mechanism of the …

E Baciocchi, A Lapi

Index: Baciocchi, Enrico; Lapi, Andrea Tetrahedron Letters, 1999 , vol. 40, # 29 p. 5425 - 5428

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Citation Number: 11

Abstract

ABSTRACT: The ce: simple-parahIO promoted oxidation of N-methyl-9-t-butylacridase (1) catalyzed by tetrakis (pentafluorophenyl) porphyrin iron (III) leads first to 9-t-butylacridane and then to acridine. It is suggested that 1 can represent a reliable machanistic probe to detect the intervention of radical cations in the oxidation of aromatic amines.

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