The Journal of organic chemistry

Iodophosphoryloxylation of carbon-carbon multibonds and its application to glycals

T Muraki, M Yokoyama, H Togo

Index: Muraki, Takahito; Togo, Hideo; Yokoyama, Masataka Journal of Organic Chemistry, 1999 , vol. 64, # 8 p. 2883 - 2889

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Citation Number: 21

Abstract

Iodophosphoryloxylation of carbon-carbon multibonds was attempted. Alkynes and cyclohexene were converted to the corresponding 1, 2-iodophosphoryloxylated compounds in moderate to good yields with a trivalent iodine compound/iodine system, while glucal gave mainly the corresponding iodohydrin compound in this system. However, 2-deoxy-2- iodoglycosyl diphenylphosphinates were obtained from the corresponding glycals with a ...