Journal of the American Chemical Society 2006-09-13

A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity.

Shengqian Ma, Hong-Cai Zhou

Index: J. Am. Chem. Soc. 128 , 11734, (2006)

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Abstract

A metal-organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2 and CH4 adsorption enthalpies of PCN-9 are among the highest reported thus far.