Palladium-catalyzed carbonylative coupling of aryl triflates with organostannanes

AM Echavarren, JK Stille

Index: Echavarren,A.M.; Stille,J.K. Journal of the American Chemical Society, 1988 , vol. 110, p. 1557

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Citation Number: 206

Abstract

Abstract: The palladium-catalyzed coupling reaction of aryl triflates with organastannanes in the presence of carbon monoxide and lithium chloride takes place under relatively mild conditions to give good yields of aryl ketones. Dichloro [1, l'-bis (di-phenylphosphino) ferrocene] palladium (II) is unique in that it is the only one of several catalysts tried that gives consistently high yields of product. The coupling takes place even in the presence of ...

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Detail

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