Organic Letters 2007-08-30

First total synthesis and structural reassignment of (-)-aplysiallene.

Jian Wang, Brian L Pagenkopf

Index: Org. Lett. 9 , 3703, (2007)

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Abstract

The first total synthesis of (-)-aplysiallene has been completed in 16 steps and features a key sequential Mukaiyama aerobic oxidative cyclization to prepare the fused bis-THF core. The original stereochemical assignment has been revised as shown.

Structure	Name/CAS No.	Molecular Formula	Articles
	(Triphenylphosphoranylidene)acetaldehyde CAS:2136-75-6	C₂₀H₁₇OP

Total synthesis of borrelidin.
2007-04-13
[J. Org. Chem. 72 , 2744, (2007)]

H.J. Bestmann et al.
[Angew. Chem. Int. Ed. Engl. 91 , 748, (1979)]

First total synthesis and structural reassignment of (-)-aplysiallene.

Abstract

Related Compounds