Organic Letters 2003-12-25

Direct carbamoylation of alkenyl halides.

Robert F Cunico, Bikash C Maity

Index: Org. Lett. 5 , 4947, (2003)

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Abstract

Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text]

Structure	Name/CAS No.	Molecular Formula	Articles
	Bis(tri-t-butylphosphine)palladium CAS:53199-31-8	C₂₄H₅₄P₂Pd

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Negishi, E.-I.; Shi, J.-C.; Zeng, X.
[Tetrahedron 61 , 9886, (2005)]

Direct carbamoylation of alkenyl halides.

Abstract

Related Compounds