Organic letters

Electrochemical Carboxylation of N-(2-Bromopropionyl)-4 R-phenyloxazolidin-2-one: An Efficient Route to Unsymmetrical Methylmalonic Ester Derivatives

M Feroci, A Inesi, M Orsini, L Palombi

Index: Carelli, Italo; Curulli, Antonella; Inesi, Achille; Zeuli, Errico Journal of Chemical Research, Miniprint, 1990 , # 3 p. 620 - 644

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Citation Number: 13

Abstract

Electrochemical carboxylation of N-(2-bromopropionyl)-4 R-phenyloxazolidin-2-one aimed at the synthesis and chiral resolution of unsymmetrical methylmalonic ester derivatives is described. The presence of the Evans' chiral auxiliary permits an easy resolution of the

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~44%

~42%

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~24%

~42%

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~24%

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