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e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Synthesis of. alpha.-keto esters via palladium-catalyzed double carbonylation

T Sakakura, H Yamashita, T Kobayashi…

Index: Journal of Organic Chemistry, , vol. 52, # 26 p. 5733 - 5740

Full Text: HTML

Citation Number: 53

Abstract

... e Cyclohexanol. (HNu: RZNH, RNHZ, ROH, HzO) and comprehensive research on the double carbonylation has revealed that a-keto esters can also be synthesized from organic halides and ... 5734 J. Org. Chem., Vol. 52, No. 26, 1987 ... 65 I 4 w, 120 L, I i&-J 0 -0.3 -0.2 -0.1 0.0 0.1 ...

 Related Synthetic Route
Iodobenzene Structure

591-50-4

Iodobenzene

carbon monoxide Structure

201230-82-2

carbon monoxide

Butanol Structure

71-36-3

Butanol

~%

n-Butyl benzoate Structure

136-60-7

n-Butyl benzoate

Detail
carbon monoxide Structure

201230-82-2

carbon monoxide

2-phenylvinyl iodide Structure

101349-79-5

2-phenylvinyl iodide

Isopropanol Structure

67-63-0

Isopropanol

~58%

Isopropyl (2E)-3-phenylacrylate Structure

7780-06-5

Isopropyl (2E)-...

Detail
Iodobenzene Structure

591-50-4

Iodobenzene

Ethanol Structure

64-17-5

Ethanol

carbon monoxide Structure

201230-82-2

carbon monoxide

~54%

Ethyl oxophenylacetate Structure

1603-79-8

Ethyl oxophenyl...

Detail
Iodobenzene Structure

591-50-4

Iodobenzene

isobutanol Structure

78-83-1

isobutanol

carbon monoxide Structure

201230-82-2

carbon monoxide

~%

Isobutyl benzoate Structure

120-50-3

Isobutyl benzoate

Detail
Methanol Structure

67-56-1

Methanol

Iodobenzene Structure

591-50-4

Iodobenzene

carbon monoxide Structure

201230-82-2

carbon monoxide

~16%

Methyl benzoate Structure

93-58-3

Methyl benzoate

Detail
Iodobenzene Structure

591-50-4

Iodobenzene

Ethanol Structure

64-17-5

Ethanol

carbon monoxide Structure

201230-82-2

carbon monoxide

~12%

Ethyl oxophenylacetate Structure

1603-79-8

Ethyl oxophenyl...

Detail
Bromobenzene Structure

108-86-1

Bromobenzene

Isopropanol Structure

67-63-0

Isopropanol

~62%

Isopropyl Benzoate Structure

939-48-0

Isopropyl Benzoate

ISOPROPYLPHENYLGLYOXYLATE Structure

31197-66-7

ISOPROPYLPHENYL...

Iodobenzene Structure

591-50-4

Iodobenzene

carbon monoxide Structure

201230-82-2

carbon monoxide

Isopropanol Structure

67-63-0

Isopropanol

~3%

Isopropyl Benzoate Structure

939-48-0

Isopropyl Benzoate

Detail
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Detail Synthetic Route


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