Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2013-04-01

Multi-phonon assisted upconversion emission and power dependence studies in LaF3:Er3+ phosphor.

A K Singh, K Kumar, A C Pandey, S B Rai, D Kumar

Index: Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 106 , 236-41, (2013)

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Abstract

LaF3:Er3+ phosphor is synthesized through chemical precipitation method and its upconversion (UC) emission studies have carried out using 532-nm excitation. Phosphor has shown two-photon absorption UV bands at the 325 nm, 342 nm, 383 nm, 403 nm and 411 nm wavelengths. At relatively higher excitation powers multi-phonon assisted energy migration from 2H11/2 (4S3/2) level to the upper 4F3/2, 4F5/2 and 4F7/2 levels has observed and this energy migration opened new channel of emission at 440 nm, 453 nm and 488 nm due to the 4F3/2→4I15/2, 4F5/2→4I15/2 and 4F7/2→4I15/2 transitions, respectively. Temperature dependent UC measurement is also done and observed emission pattern is correlated with the power dependence studies. Upconversion bands at 411 and 488 nm wavelengths have shown reversal in intensity as either excitation power or sample temperature is increased and hence these two bands are found to act as optical switch. Planck blackbody like continuum emission has also observed at higher excitation powers.Copyright © 2013 Elsevier B.V. All rights reserved.