Synthesis of binaphthyl derivatives through radical cation formation

M Tanaka, H Nakashima, M Fujiwara…

Index: Tanaka, Mutsuo; Nakashima, Hideki; Fujiwara, Masahiro; Ando, Hisanori; Souma, Yoshie Journal of Organic Chemistry, 1996 , vol. 61, # 2 p. 788 - 792

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Citation Number: 31

Abstract

Aromatic radical cations are well-known species in electrochemical and gas phase reactions that produce biaryls through a coupling reaction with aromatic compounds, and the existence of aromatic radical cations in the liquid phase has recently been proposed on the basis of spectroscopic studies. 1 Metal salts such as CuCl2, 2 Tl (OCOCF3) 3, 3 and Mn [CH (COCH3) 2] 3 4 and Lewis acids such as AlCl3, 5 FeCl3, 6 and SbCl3 7 are reported to be ...