The influence of the sacrificial anode nature on the mechanism of electrochemical arylation and alkylation of white phosphorus

DG Yakhvarov, YH Budnikova, DI Tazeev…

Index: Yakhvarov; Budnikova; Tazeev; Sinyashin Russian Chemical Bulletin, 2002 , vol. 51, # 11 p. 2059 - 2064

Full Text: HTML

Citation Number: 7

Abstract

Abstract The material of the sacrificial anode has a substantial effect on the nature and yield of the target products of electrochemical phosphorylation of organic halides by white phosphorus in the presence of the nickel complexes with 2, 2"-bipyridine. The use of the zinc anode results in the products with tricoordinated phosphorus, viz., triorganylphosphines, the reaction on the aluminum anode affords triorganylphosphine oxides, and the presence of ...