Molecules 2012-01-01

Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature.

Chun-Wei Kuo, Min-Tsang Hsieh, Shijay Gao, Yi-Ming Shao, Ching-Fa Yao, Kak-Shan Shia

Index: Molecules 17(11) , 13662-72, (2012)

Full Text: HTML

Abstract

Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.