Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2011-01-01

Surface-enhanced Raman spectroscopy of omethoate adsorbed on silver surface.

Hee Jin Kim, Chul Jae Lee, Mohammad Rezaul Karim, Mak Soon Kim, Mu Sang Lee

Index: Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 78(1) , 179-84, (2011)

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Abstract

We have investigated surface-enhanced Raman spectroscopy (SERS) spectrum of Omethoate (O,O-dimethyl-S-methylcarbamoylmethylthiophosphate). It is found significant signals in the ordinary Raman spectrum for solid-state Omethoate as well as strong vibrational signals absorbed on the silver sol surface which is prepared by γ-irradiation technique at a very low concentration. Effects of pH and anions (Cl-, Br-, I-) on the adsorption orientation are investigated as well. Two different adsorption mechanisms are deduced, depending on the experimental conditions. The sulfur atom or the sulfur and two oxygen atoms are adsorbed onto the silver sol surface. Among halide ions, Br- and I- are more strongly adsorbed onto the silver sol surface. As a result, the adsorption of Omethoate is less effective due to their steric hindrance.Crown Copyright © 2010. Published by Elsevier B.V. All rights reserved.