RSC Advances

IBX works efficiently under solvent free conditions in ball milling

TK Achar, S Maiti, P Mal

Index: Achar, Tapas Kumar; Maiti, Saikat; Mal, Prasenjit RSC Advances, 2014 , vol. 4, # 25 p. 12834 - 12839

Full Text: HTML

Citation Number: 12

Abstract

IBX (2-iodoxybenzoic acid), discovered in 1893, is an oxidant in synthetic chemistry whose extensive use is impeded by its explosiveness at high temperature and poor solubility in common organic solvents except DMSO. Since the discovery of Dess–Martin Periodinane in 1983, several modified IBX systems have been reported. However, under ball milling conditions, IBX works efficiently with various organic functionalities at ambient ...