Chemische Berichte

Alkyleisen??und Alkylcobalt??Reagenzien, VII. Über die Substitution des Halogens von Alkenylchloriden, Alkenylfluoriden und Alkinylhalogeniden durch Reagenzien …

T Kauffmann, R Sälker, KU Voß

Index: Kauffmann, Thomas; Saelker, Reiner; Voss, Karl-Uwe Chemische Berichte, 1993 , vol. 126, # 6 p. 1447 - 1452

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Citation Number: 5

Abstract

Me4FeLiz and Me, CoLi,, which are favourable reagents for ethyne (12), 1-bromo-2- phenylethyne (13), and l-chloro-3-the substitution of Br in alkenyl bromide~[l-~], also proved to phenoxypropyne (15) by methyl (yields 70, 46, and 80%, re-be favourable for the substitution of the halogen in alkenyl spectively). Substitution of the halogen in 12 by the n- butyl, chlorides (yields 68-99%; nearly complete retention of con-n-octyl, and phenyl ...