Tetrahedron: Asymmetry

Lewis acid mediated asymmetric Diels–Alder reactions of chiral 2-phosphonoacrylates

JL Zhu, PE Chen, HW Huang

Index: Tetrahedron Asymmetry, , vol. 24, # 1 p. 23 - 36

Full Text: HTML

Citation Number: 5

Abstract

... Tetrahedron: Asymmetry. Volume 24, Issue 1, 15 January 2013, Pages 23–36. ... So far, these types of chiral precursors have only been used in the 1,4-addition reactions with dimethyloxosulfonium methylide for preparing cyclopropane derivatives, 11 and not reported for the Diels ...

 Related Synthetic Route
N/A Structure

1420376-74-4

N/A

~%

N/A Structure

1420376-86-8

N/A

N/A Structure

1420376-89-1

N/A

(-)-8-Phenylmenthol Structure

65253-04-5

(-)-8-Phenylmenthol

N/A Structure

155795-48-5

N/A

~%

(-)-8-Phenylmenthol Structure

65253-04-5

(-)-8-Phenylmenthol

N/A Structure

1420376-56-2

N/A

~%

(-)-8-Phenylmenthol Structure

65253-04-5

(-)-8-Phenylmenthol

N/A Structure

155795-48-5

N/A

~%

N/A Structure

1420376-89-1

N/A

(-)-8-Phenylmenthol Structure

65253-04-5

(-)-8-Phenylmenthol

N/A Structure

1420376-56-2

N/A

~%

N/A Structure

1420376-89-1

N/A

(-)-8-Phenylmenthol Structure

65253-04-5

(-)-8-Phenylmenthol

(1R,2S,5R)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexyl (1S,2S)-1-(diethoxyphosphoryl)-2-methylcyclohex-3-ene carboxylate Structure

1420376-80-2

(1R,2S,5R)-5-me...

~%

N/A Structure

162868-74-8

N/A

(-)-8-Phenylmenthol Structure

65253-04-5

(-)-8-Phenylmenthol

(1R,2S,4R)-2-(diethoxy-phosphoryl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-2-phenyl-cyclohexyl ester Structure

1420376-71-1

(1R,2S,4R)-2-(d...

~%

(1R,2S)-2-phenylcyclohexanol Structure

98919-68-7

(1R,2S)-2-pheny...

N/A Structure

1420376-86-8

N/A

N/A Structure

1420376-89-1

N/A

N/A Structure

1420376-31-3

N/A

~%

(1R,2S)-2-phenylcyclohexanol Structure

98919-68-7

(1R,2S)-2-pheny...

N/A Structure

1420376-89-1

N/A

2-(diethoxy-phosphoryl)acrylic acid (1R,2S)-2-phenyl-cyclohexyl ester Structure

1420376-53-9

2-(diethoxy-pho...

~%

(1R,2S)-2-phenylcyclohexanol Structure

98919-68-7

(1R,2S)-2-pheny...

N/A Structure

1420376-89-1

N/A

(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl (1R,2S,4R)-2-(diethoxyphosphoryl)bicyclo[2.2.1]hept-5-ene-2-carboxylate Structure

1420376-77-7

(1R,2S,5R)-2-is...

~%

L-Menthol Structure

2216-51-5

L-Menthol

N/A Structure

1420376-86-8

N/A

N/A Structure

1420376-89-1

N/A

(diethoxy-phosphoryl)-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester Structure

141540-20-7

(diethoxy-phosp...

~%

L-Menthol Structure

2216-51-5

L-Menthol

2-(diethoxy-phosphoryl)-acrylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester Structure

1420376-59-5

2-(diethoxy-pho...

~%

L-Menthol Structure

2216-51-5

L-Menthol

(diethoxy-phosphoryl)-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester Structure

141540-20-7

(diethoxy-phosp...

~%

L-Menthol Structure

2216-51-5

L-Menthol

N/A Structure

1420376-89-1

N/A

(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl (1S,2S)-1-(diethoxyphosphoryl)-2-methylcyclohex-3-enecarboxylate Structure

1420376-83-5

(1R,2S,5R)-2-is...

~%

L-Menthol Structure

2216-51-5

L-Menthol

N/A Structure

162868-74-8

N/A

(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl (1R,2S,4R)-2-(diethoxyphosphoryl)bicyclo[2.2.1]hept-5-ene-2-carboxylate Structure

1420376-77-7

(1R,2S,5R)-2-is...

~%

L-Menthol Structure

2216-51-5

L-Menthol

N/A Structure

139402-56-5

N/A

2-(diethoxy-phosphoryl)-acrylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester Structure

1420376-59-5

2-(diethoxy-pho...

~%

L-Menthol Structure

2216-51-5

L-Menthol

N/A Structure

1420376-89-1

N/A


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