Journal of organometallic chemistry

Catalysis of hydrosilylation: VII. Catalysis of hydrosilylation of C C bonds by ruthenium phosphine complexes

B Marciniec, J Guliński

Index: Marciniec, Bogdan; Gulinski, Jacek Journal of Organometallic Chemistry, 1983 , vol. 253, # 3 p. 349 - 362

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Citation Number: 32

Abstract

Abstract A full account of the catalysis of hydrosilylation of the C C bond in olefins, their derivatives with functional groups as well as in vinyl-trisubstituted silanes by ruthenium (II) and ruthenium (III) phosphine precursors is given. The ruthenium complexes are far more efficient catalysts for the hydrosilylation of 1-alkenes and vinyl-substituted silanes than for the substituted olefins and unsaturated esters. General features characterizing all ...