Smiles rearrangement for the synthesis of diarylamines.

…, HL Wei, H Yang, DS Shin, LY Wang…

Index: Tian, Xiao; Wu, Ren-Min; Liu, Gang; Li, Zhu-Bo; Wei, He-Lin; Yang, Hao; Shin, Dong-Soo; Wang, Li-Ying; Zuo, Hua Arkivoc, 2011 , vol. 2011, # 10 p. 118 - 126

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Citation Number: 5

Abstract

Abstract A protocol for the one-pot synthesis of diarylamines via Smiles rearrangement under microwave irradiation has been developed. Various diarylamines were effectively synthesized starting from readily available substituted phenols, arylamines and chloroacetyl chloride in moderate to good yields (58-92%).[ABSTRACT FROM AUTHOR]

~91%

~77%

~67%

~76%

~75%

~81%

~80%

~88%

~56%

~86%

~88%

~69%

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