Acyl iodides in organic synthesis. Reactions with morpholine, piperidine, and N-hydrocarbylpiperidines

MG Voronkov, IP Tsyrendorzhieva…

Index: Voronkov; Tsyrendorzhieva; Rakhlin Russian Journal of Organic Chemistry, 2010 , vol. 46, # 6 p. 794 - 797

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Citation Number: 7

Abstract

Abstract Acyl iodides RCOI (R= Me, Ph) reacted with morpholine and piperidine to give the corresponding N-acyl derivatives and morpholine or piperidine hydroiodides. Reactions of acyl iodides with N-methyl-and N-ethylpiperidines involved cleavage of the exocyclic RN bond with formation of N-acylpiperidine and alkyl iodide and were accompanied (to insignificant extent) by cleavage of the endocyclic NC bond, leading to N-alkyl-N-(5- ...