Journal of Fluorescence 2011-01-01

Phenoxazine based units--synthesis, photophysics and electrochemistry.

Anna Nowakowska-Oleksy, Jadwiga Sołoducho, Joanna Cabaj

Index: J. Fluoresc. 21 , 169-78, (2011)

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Abstract

A few new phenoxazine-based conjugated monomers were synthesized, characterized, and successfully used as semiconducting materials. The phenoxazine-based oligomers have low ionization potentials or high-lying HOMO levels (~4.7 eV), which were estimated from cyclic voltammetry. Conjugated oligomers offer good film-forming, mechanical and optical properties connected with their wide application. These results demonstrate that phenoxazine-based conjugated mers are a promising type of semiconducting and luminescent structures able to be used as thin films in organic electronics.