Canadian Journal of Chemistry

Study of trichloronitrosomethane: regioselective cycloadditions of 2-substituted-1, 3-butadienes

CT Lin, WJ Hsu

Index: Lin, Cheng-Tung; Hsu, Wen-Jei Canadian Journal of Chemistry, 1989 , vol. 67, p. 2153 - 2161

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Citation Number: 7

Abstract

The regioselectivity of cycloaddition reactions of trichloronitrosomethane (1) with 2-alkyl (R= Me, Et, i-Pr, t-Bu, CF3, Bz, and Cl) and 2-aryl (Ar= Ph, 4-CH3OPh, 4-CH3Ph, 3-CH3Ph, and 4-ClPh) 1, 3-butadienes is described. The orientation of cycloaddition is substituent