Mechanism of the diphenyldisulfone-catalyzed isomerization of alkenes. Origin of the chemoselectivity: experimental and quantum chemistry studies

D Markovic, A Varela-Álvarez, JA Sordo…

Index: Journal of the American Chemical Society, , vol. 128, # 24 p. 7782 - 7795

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Citation Number: 18

Abstract

... Journal of the ... 2006, 128 (24), pp 7782–7795. DOI: 10.1021/ja0579210. Publication Date (Web): May 24, 2006. Copyright © 2006 American Chemical Society. ... not isomerized at all, whereas 2-alkyl substituted alk-1-enes were isomerized (Scheme 2). This discovery led us to invent ...

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