e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon− Halogen Bonds Using Silylium Catalysis

C Douvris, CM Nagaraja, CH Chen…

Index: Journal of the American Chemical Society, , vol. 132, # 13 p. 4946 - 4953

Full Text: HTML

Citation Number: 88

Abstract

... Journal of the ... Soc. , 2010, 132 (13), pp 4946–4953. DOI: 10.1021/ja100605m. Publication Date (Web): March 10, 2010. Copyright © 2010 American Chemical Society. ... co-solvent” in Table 1). The results in entries F8, F9, F11, F16, F17, and F19 were communicated by us in 2008 ...

1H,1H,1H,2H,2H-NONAFLUOROHEXANE Structure

1H,1H,1H,2H,2H-...

~%

N-hexane Structure

Methylcyclopentane Structure

Methylcyclopentane

cyclohexane Structure

(3,3,3-trifluoropropyl)benzene Structure

(3,3,3-trifluor...

benzene Structure

~%

Dibenzylmethane Structure

Dibenzylmethane

1-Chlorooctane Structure

1-Bromononane Structure

1-fluoro-Decane Structure

1-fluoro-Decane

~94%

Octane Structure

Detail

2,3,4,5,6-Pentafluorobenzylchloride Structure

2,3,4,5,6-Penta...

~82%

Benzene,1,2,3,4,5-pentafluoro-6-methyl- Structure

Benzene,1,2,3,4...

Chlorocyclohexane Structure

Chlorocyclohexane

~35%

Methylcyclopentane Structure

Methylcyclopentane

cyclohexane Structure

1H,1H,1H,2H,2H-NONAFLUOROHEXANE Structure

1H,1H,1H,2H,2H-...

~%

N-hexane Structure

Methylcyclopentane Structure

Methylcyclopentane

cyclohexane Structure

1H,1H,1H,2H,2H-NONAFLUOROHEXANE Structure

1H,1H,1H,2H,2H-...

~%

N-hexane Structure

Methylcyclopentane Structure

Methylcyclopentane

cyclohexane Structure

1-Chlorooctane Structure

1-Bromononane Structure

1-fluoro-Decane Structure

1-fluoro-Decane

~9%

Octane Structure

Detail

4-FLUOROBENZOTRICHLORIDE Structure

4-FLUOROBENZOTR...

~59%

4-Fluorotoluene Structure

4-Fluorotoluene

Chlorocyclohexane Structure

Chlorocyclohexane

~13%

Methylcyclopentane Structure

Methylcyclopentane

cyclohexane Structure

Direct conversion of alcohols to alkanes

[Journal of Organic Chemistry, , vol. 46, # 21 p. 4306 - 4307]

Direct conversion of alcohols to alkanes

[Journal of Organic Chemistry, , vol. 46, # 21 p. 4306 - 4307]

High temperature catalytic hydrogenolysis and alkylation of ...

[Canadian Journal of Chemistry, , vol. 62, p. 2540 - 2545]

High temperature catalytic hydrogenolysis and alkylation of ...

[Canadian Journal of Chemistry, , vol. 62, p. 2540 - 2545]

Direct conversion of alcohols to alkanes

[Journal of Organic Chemistry, , vol. 46, # 21 p. 4306 - 4307]