Triazole bridges as versatile linkers in electron donor–acceptor conjugates

G de Miguel, M Wielopolski, DI Schuster…

Index: De Miguel, Gustavo; Wielopolski, Mateusz; Schuster, David I.; Fazio, Michael A.; Lee, Olivia P.; Haley, Christopher K.; Ortiz, Angy L.; Echegoyen, Luis; Clark, Timothy; Guldi, Dirk M. Journal of the American Chemical Society, 2011 , vol. 133, # 33 p. 13036 - 13054

Full Text: HTML

Citation Number: 78

Abstract

Aromatic triazoles have been frequently used as π-conjugated linkers in intramolecular electron transfer processes. To gain a deeper understanding of the electron-mediating function of triazoles, we have synthesized a family of new triazole-based electron donor– acceptor conjugates. We have connected zinc (II) porphyrins and fullerenes through a central triazole moiety(ZnP–Tri–C60) each with a single change in their connection ...