Mechanistic Studies into Amine-Mediated Electrophilic Arene Borylation and Its Application in MIDA Boronate Synthesis

V Bagutski, A Del Grosso, JA Carrillo…

Index: Journal of the American Chemical Society, , vol. 135, # 1 p. 474 - 487

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Citation Number: 65

Abstract

... Journal of the ... 135 (1), pp 474–487. DOI: 10.1021/ja3100963. Publication Date (Web): December 3, 2012. Copyright © 2012 American Chemical Society. ... using iridium catalysts.(4-8) The amine-mediated intermolecular boron analogue of Friedel–Crafts chemistry represents a new ...

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Naphthalene Structure

91-20-3

Naphthalene

~%

Naphthalene-2-boronic acid pinacol ester Structure

256652-04-7

Naphthalene-2-b...

Thianaphthene Structure

95-15-8

Thianaphthene

~%

2-Benzo[b]Thiophene-2-Boronic Acid Pinacol Ester Structure

376584-76-8

2-Benzo[b]Thiop...

Pinacol Structure

76-09-5

Pinacol

Toluene Structure

108-88-3

Toluene

~%

4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane Structure

195062-57-8

4,4,5,5-Tetrame...

4,4,5,5-Tetramethyl-2-(m-tolyl)-1,3,2-dioxaborolane Structure

253342-48-2

4,4,5,5-Tetrame...

Biphenyl Structure

92-52-4

Biphenyl

~%

4-biphenylboronic acid, pinacol ester Structure

144432-80-4

4-biphenylboron...

Pinacol Structure

76-09-5

Pinacol

(4-biphenylyl)dichloroborane Structure

39767-04-9

(4-biphenylyl)d...

~%

4-biphenylboronic acid, pinacol ester Structure

144432-80-4

4-biphenylboron...

1-Methylpyrrole Structure

96-54-8

1-Methylpyrrole

~%

1-METHYL-3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-1H-PYRROLE Structure

953040-54-5

1-METHYL-3-(4,4...

Pinacol Structure

76-09-5

Pinacol

Toluene Structure

108-88-3

Toluene

~%

4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane Structure

195062-57-8

4,4,5,5-Tetrame...

4,4,5,5-Tetramethyl-2-(m-tolyl)-1,3,2-dioxaborolane Structure

253342-48-2

4,4,5,5-Tetrame...

Pinacol Structure

76-09-5

Pinacol

Isobutylbenzene Structure

538-93-2

Isobutylbenzene

~%

2-(4-Isobutylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Structure

1033753-01-3

2-(4-Isobutylph...

2-(3-Isobutylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Structure

1416243-14-5

2-(3-Isobutylph...


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