Journal of the American Chemical Society 2008-10-29

Synthesis of hexagonal nickel hydroxide nanosheets by exfoliation of layered nickel hydroxide intercalated with dodecyl sulfate ions.

Shintaro Ida, Daisuke Shiga, Michio Koinuma, Yasumichi Matsumoto

Index: J. Am. Chem. Soc. 130(43) , 14038-9, (2008)

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Abstract

One-nanometer-thick nickel hydroxide nanosheets were prepared by exfoliation of layered nickel hydroxides intercalated with dodecyl sulfate (DS) ions. The shape of the nanosheets was hexagonal, as was that of the layered nickel hydroxides intercalated with DS ions. The nickel hydroxide nanosheets exhibited charge-discharge properties in strong alkaline electrolyte. The morphology of the nanosheet changed during the electrochemical reaction.