Dalton Transactions (Print Edition) 2012-12-21

Temperature-dependent assemblies from a 2-D triple-stranded meso-helical layer to a 3-D chain-layer metal-organic framework.

Hong-Guang Jin, Xu-Jia Hong, Jing Li, Yuan-Zhao Yan, Yi-Ting Liu, Shi-Hai Xu, Yue-Peng Cai

Index: Dalton Trans. 41(47) , 14239-43, (2012)

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Abstract

Two different crystal forms, namely {[Dy2(mpda)3(H2O)2]·H2O}n (1) and [Dy2(mpda)3(H2O)4]n (2), were obtained from the reaction of multidentate 2,6-dimethylpyridine-3,5-dicarboxylic acid (H2mpda) with Dy2O3 at different temperatures. Structural analysis reveals that compound 1 is a 2-D triple-stranded meso-helical layer, and 2 a 3-D chain-layer framework. The fluorescent measure shows that compound 1 is a promising luminescent probe for various metals with a remarkable “on–off” switch of emission, mainly deriving from many pairs of inversely arranged 4-aza bowl-like crown ethers distributed in the 2-D helical plane. Moreover, compound 1 presents noticeable hydrogen-sorption at medium pressure.