Organic Letters 2012-04-06

ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.

Srimanta Manna, Soham Maity, Sujoy Rana, Soumitra Agasti, Debabrata Maiti

Index: Org. Lett. 7th ed., 14 , 1736-1739, (2012)

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Abstract

An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and functional groups make this method advantageous. Due to its simplicity, we expect to find application of this method in synthesis.