Journal of the American Chemical Society 2004-10-13

A photopatternable pentacene precursor for use in organic thin-film transistors.

Kevin P Weidkamp, Ali Afzali, Rudolf M Tromp, Robert J Hamers

Index: J. Am. Chem. Soc. 126 , 12740, (2004)

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Abstract

We demonstrate that modifying pentacene to incorporate an acid-labile moiety into its molecular structure leads to a new precursor that can be easily deposited, photopatterned, and processed via wet-chemical methods to produce organic semiconducting devices exhibiting good electrical characteristics. Acidic conditions produced by ultraviolet illumination of a co-deposited photoacid generator greatly accelerate the local conversion of this N-sulfinyl-tert-butylcarbamate pentacene adduct back to pentacene. Photopatterned thin-film transistors exhibit carrier mobilities in excess of 0.1 cm2 V-1 s-1, making this an attractive precursor for fabrication of large-area organic electronics via solution-phase methods.