Transformation of Carboxylic Esters to Aldehydes with Sodium Tris (diethylamino) aluminum Hydride

JS Cha, JM Kim, MK Jeoung, OO Kwon…

Index: Cha, Jin Soon; Kim, Jong Mi; Jeoung, Min Kyoo; Kwon, Oh Oun; Kim, Eun Ju Organic Preparations and Procedures International, 1995 , vol. 27, # 1 p. 95 - 98

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Citation Number: 5

Abstract

The conversion of carboxylic esters into aldehydes is important in organic synthesis. A number of useful reducing agents for such a transformation have been reported, eg, lithium tri-tert-butoxyaluminum hydride,'diisobutylaluminum hydride, 2 sodium diisobutylaluminum hydride? bis (4-methyl-I-piperaziny1) aluminum hydride: and sodium diethylpiperidinylaluminum hydride? Recently, we reported that lithium rris (diethy1amino) ...

~98%

~68%

~69%

~90%

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~84%

~91%

~71%

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