Synthesis and spectroelectrochemical studies of mixed heteroleptic chelate complexes of ruthenium (II) with 1, 8-bis (2-pyridyl)-3, 6-dithiaoctane (pdto) and substituted …

…, JG Alvarado-Rodriguez, R Moreno-Esparza

Index: Ortiz-Frade, Luis A.; Ruiz-Ramirez, Lena; Gonzalez, Ignacio; Marin-Becerra, Armando; Alcarazo, Manuel; Alvarado-Rodriguez, Jose G.; Moreno-Esparza, Rafael Inorganic Chemistry, 2003 , vol. 42, # 6 p. 1825 - 1834

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Citation Number: 33

Abstract

Synthesis starting from the complex [Ru (pdto) Cl (PPh3)] Cl, characterization, spectroelectrochemical, and electrochemical studies of the [Ru (pdto) L n] Cl2 obtained were performed; L n= 4, 7-diphenyl-1, 10-phenanthroline (L1), 1, 10-phenanthroline (L2), 5, 6- dimethyl-1, 10-phenanthroline (L3), 4, 7-dimethyl-1, 10-phenanthroline (L4), and 3, 4, 7, 8- tetramethyl-1, 10-phenanthroline (L5). The crystal structure of the molecule [Ru (pdto) L2] ...