e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Perfluorocarbon fluids as solvent replacements

RD Chambers, AR Edwards

Index: Chambers, Richard D.; Edwards, Andrew R. Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 24 p. 3623 - 3627

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Citation Number: 23

Abstract

Perfluoroperhydrophenanthrene 1 may be used as a 'bulking agent'to minimise the problem of solvent recovery in halogen exchange ('Halex') reactions for the preparation of octafluorocyclopentene 8, and chlorofluoro-pyridine,-pyrimidine and-benzene derivatives. New 'one-pot'procedures for the syntheses of hexaflu

Hexachlorobenzene Structure

Hexachlorobenzene

~83%

Benzene,1,3,5-trichloro-2,4,6-trifluoro- Structure

Benzene,1,3,5-t...

Perchloropyridine Structure

Perchloropyridine

~93%

3,5-Dichloro-2,4,6-trifluoropyridine Structure

3,5-Dichloro-2,...

2,3-dichlorohexafluoro-2-butene Structure

2,3-dichlorohex...

~%

(Z)-1,1,1,2,3,4,4,4-octafluorobut-2-ene Structure

(Z)-1,1,1,2,3,4...

(E)-1,1,1,2,3,4,4,4-octafluorobut-2-ene Structure

(E)-1,1,1,2,3,4...

Hexachloro-1,3-butadiene Structure

Hexachloro-1,3-...

~68%

hexafluorocyclobutene Structure

hexafluorocyclo...

1,2,3,3,4,4,5,5-octachlorocyclopentene Structure

1,2,3,3,4,4,5,5...

~89%

perfluorocyclopentene Structure

perfluorocyclop...

2,4,5,6-Tetrachloropyrimidine Structure

2,4,5,6-Tetrach...

~89%

5-Chloro-2,4,6-trifluoropyrimidine Structure

5-Chloro-2,4,6-...

2,3-dichlorohexafluoro-2-butene Structure

2,3-dichlorohex...

~%

(Z)-1,1,1,2,3,4,4,4-octafluorobut-2-ene Structure

(Z)-1,1,1,2,3,4...

(E)-1,1,1,2,3,4,4,4-octafluorobut-2-ene Structure

(E)-1,1,1,2,3,4...

Chloro-and Bromo-defluorination of Hexafluorobenzene and Oct...

[Russian Journal of Organic Chemistry, , vol. 40, # 8 p. 1117 - 1120]