Journal of fluorine chemistry

Reactions of Trifluoronitrosomethane with bistrifluoromethylphosphorus compounds,(CF 3) 2 PX (where x= H, Cl, CF 3)

HG Ang, KK So

Index: ANG, H. G.; SO, K. K. Journal of Fluorine Chemistry, 1985 , vol. 27, p. 451 - 460

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Citation Number: 9

Abstract

Abstract Trifluoronitrosomethane reacts with bis (trifluoromethyl) phosphine to give (CF 3) 2 P (O) N (OH) CF 3 and a small amount of (CF 3) 2 NOH. On the other hand, the reactions with tris (trifluoromethyl) phosphine and bis (trifluoromethyl) chlorophosphine afford (CF 3) 2 NOP (O) CF 3 N (CF 3) 2 and (CF 3) 2 NP (O)(CF 3) Cl respectively. Isomerisation of Full- size image (1 K)