Journal of Colloid and Interface Science 2013-09-15

Ceria and titania incorporated silica based catalyst prepared from rice husk: adsorption and photocatalytic studies of methylene blue.

Farook Adam, Lingeswarran Muniandy, Radhika Thankappan

Index: J. Colloid. Interface Sci. 406 , 209-16, (2013)

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Abstract

Titania and ceria incorporated rice husk silica based catalyst was synthesized via sol-gel method using CTAB and glycerol as surface directing agents at room temperature and labeled as RHS-50Ti10Ce. The catalyst was used to study the adsorption and photodegradation of methylene blue (MB) under UV irradiation. The powder XRD pattern of RHS-50Ti10Ce was much broader (2θ=25-30°) than that of the parent RHS (2θ=22°). The catalyst exhibited type IV isotherm with H3 hysteresis loop, and the TEM images showed partially ordered pore arrangements. The TGA-DTG thermograms confirmed the complete removal of the templates after calcination at 500°C. RHS-50Ti10Ce exhibited excellent adsorption capability with more than 99% removal of MB from a 40 mg L(-1) solution in just 15 min. It also decolorized an 80 mg L(-1) MB solution under UV irradiation in 210 min, which was comparable with the commercialized pure anatase TiO2.Copyright © 2013 Elsevier Inc. All rights reserved.