Bulletin of Environmental Contamination and Toxicology 2014-11-01

Diazinon and permethrin mitigation across a grass-wetland buffer.

M T Moore, R Kröger, M A Locke, R E Lizotte, S Testa, C M Cooper

Index: Bull. Environ. Contam. Toxicol. 93(5) , 574-9, (2014)

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Abstract

Vegetated buffers of different designs are often used as edge-of-field treatment practices to remove pesticides that may be entrained in agricultural runoff. However, buffer system efficacy in pesticide runoff mitigation varies widely due to a multitude of factors including, but not limited to, pesticide chemistry, vegetation composition, and hydrology. Two experimental systems, a control (no vegetation) and a grass-wetland buffer system, were evaluated for their ability to retain diazinon and permethrin associated with a simulated storm runoff. The two systems were equally inefficient at retaining diazinon (mean 9.6 % retention for control and buffer). Grass-wetland buffers retained 83 % and 85 % of cis- and trans-permethrin masses, respectively, while the control only retained 39 % and 44 % of cis- and trans-permethrin masses, respectively. Half-distances (the distance required to decrease pesticide concentration by one-half) for both permethrin isomers were 26 %-30 % shorter in grass buffers (22-23 m) than in the control (32 m). The current study demonstrates treatment efficacy was a function of pesticide properties with the more strongly sorbing permethrin retained to a greater degree. The study also demonstrates challenges in remediating multiple pesticides with a single management practice. By using suites of management practices, especially those employing vegetation, better mitigation of pesticide impacts may be accomplished.

Related Compounds

Structure Name/CAS No. Articles
Permethrin Structure Permethrin
CAS:52645-53-1
Diazinon Structure Diazinon
CAS:333-41-5
trans-permethrin Structure trans-permethrin
CAS:61949-77-7
cis-Permethrin Standard Structure cis-Permethrin Standard
CAS:61949-76-6