Journal of the American Chemical Society

Derivatives of Aminomethanethiol

A Binz, LH Pence

Index: Binz; Pence Journal of the American Chemical Society, 1939 , vol. 61, p. 3134,3137

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Citation Number: 5

Abstract

Hydroxymethaaefbiol, HOCHaH, was as- sumed by Bawnano' to be formed as an unstable intermediate on treating formaldehyde with hy- drogen sulfide, and he showed that the reaction proceeds to insolubk tsithhfosmaldehyde, HCHO + H2S -+ HOCHaSH + (CH2S)a. Since tri- ... Another method, however, was successful. When piperidine was added to formaldehyde and the 1-piperidinemethanol thus obtained treated with hydrogen sulfide, a vigorous reaction with strong evolution of ...