Study of oxidation of terminal unsaturated compounds by reagents based on dimethylsulfoxide

EA Krasnokutskaya, W Habicher…

Index: Krasnokutskaya; Habicher; Yusubov; Filimonov Russian Journal of Organic Chemistry, 1997 , vol. 33, # 2 p. 153 - 157

Full Text: HTML

Citation Number: 0

Abstract

The products of reactions of styrene, phenylacetylene, and 1-bromo-1-phenylethane with HBr and Br 2 in DMSO were studied for the first time by high-performance liquid chromatography and gas chromatography-mass spectrometry. Phenylglyoxal is the main product in the reactions with styrene and bromophenylethane, while dibromostyrenes are formed as the main products in the reaction with phenylacetylene. Schemes of the ...