Synlett

An Efficient Conversion of Allyl Esters to Urethanes with Pd Catalyst

H Okumoto, S Nishihara, S Yamamoto, H Hino…

Index: Okumoto, Hiroshi; Nishihara, Satoshi; Yamamoto, Sinya; Hino, Hirokazu; Nozawa, Akihiro; Suzuki, Akira Synlett, 2000 , # 7 p. 991 - 992

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Citation Number: 8

Abstract

Abstract: Reaction of allyl esters in a proper alcohol with Pd catalyst in the presence of (PhO) 2P (O) N3 and NaN3 at 80 C directly gave urethanes. The reactions in t-BuOH afforded amines protected with Boc. Key words: azides, allyl complexes, urethanes, palladium, catalysis

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