Direct synthesis and characterization of novel homo-and heterometallic mixed-ligand tetrazolate complexes, Cu (en)(tz) 2 and Cu (en) 2 Zn (tz) 4 [en= …

…, SV Voitekhovich, AS Lyakhov, LS Ivashkevich…

Index: Mosalkova, Anastasiya P.; Voitekhovich, Sergei V.; Lyakhov, Alexander S.; Ivashkevich, Ludmila S.; Degtyarik, Mikhail M.; Gaponik, Pavel N.; Ivashkevich, Oleg A. Inorganic Chemistry Communications, 2009 , vol. 12, # 10 p. 998 - 1000

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Citation Number: 4

Abstract

For the first time, tetrazolate complexes have been prepared by direct synthesis. Two novel homo-and heterometallic mixed-ligand complexes, Cu (en)(tz) 2 and Cu (en) 2Zn (tz) 4, have been synthesized using tetrazole (Htz), ethylenediamine (en), metallic copper and zinc oxide as starting materials. Both tetrazolates were characterized by single-crystal X-ray diffraction, IR spectroscopy and thermal analysis. The complexes present 1D coordination ...