Synthesis of allyl 2-dialkylamino-4-pentenoates and their analogs via Stevens rearrangement

AV Babakhanyan, LG Shakhbazyan…

Index: Babakhanyan; Shakhbazyan; Grigoryan; Kocharyan Russian Journal of Organic Chemistry, 2003 , vol. 39, # 9 p. 1227 - 1230

Full Text: HTML

Citation Number: 1

Abstract

Abstract Stevens rearrangement of ammonium salts containing an allyloxycarbonylmethyl group in benzene in the presence of sodium phenoxide yields allyl 2-dialkylamino-4- pentenoates. The rearrangement in the presence of sodium methoxide is accompanied by transesterification to afford methyl 2-dialkylamino-4-pentenoates.

N-Alkylation and [2, 3]-sigmatropic rearrangement of N-allyl...

[Coldham, Iain; Middleton, Mark L.; Taylor, Philip L. Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 20 p. 2951 - 2952]

Investigations into the [2, 3]-aza-Wittig rearrangement of N...

[Coldham, Iain; Middleton, Mark L.; Taylor, Philip L. Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2817 - 2821]