The Journal of Organic Chemistry

Vinylic cations from solvolysis. X. SN1 and nucleophilic addition-elimination routes for 9-(. alpha.-haloarylidene) fluorenes

Z Rappoport, A Gal

Index: Rappoport,Z.; Gal,A. Journal of Organic Chemistry, 1972 , vol. 37, # 8 p. 1174 - 1181

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Citation Number: 19

Abstract

Results Synthesis.---The triarylhaloethylenes l-Cl, 1-Br, and 3-Br were prepared by halogenation-dehydrohalogena-tion of the corresponding ethylenes without isolation of the ct., p-dihalides. 9'11, 14 The fluorenylidene derivative 4-Br was prepared similarly from the isolated a,@-dibromide. The dibromide 5-Br and the corresponding dichloride 5-C1 were prepared by adding the halogen to 9-anisylidenefluorenej but their analysis and nmr ...