A series of luminescent molecules were presented employing the tetrahedral structural motif of the silicon atom, which further connected different N-containing heterocycle functional groups in their periphery using phenyl rings as the bridges. These compounds included three kinds of N-heterocycle functional silanes: imidazole derivatives (1a–h), pyrazole derivatives (2a–e) and benzimidazole derivatives (3a–b), and their structures were fully ...