e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Evaluation of Aromatic Amination Catalyzed by Palladium on Carbon: A Practical Synthesis of Triarylamines

Y Monguchi, K Kitamoto, T Ikawa…

Index: Advanced Synthesis and Catalysis, , vol. 350, # 17 p. 2767 - 2777

Full Text: HTML

Citation Number: 40

Abstract

... phenylmorpholine, whereas the bulkier and stiffer bidentate phosphine ligands efficiently activat- ed the catalysis (entries 16 ... aryl bromides or aryl chlorides using Pd/C as a catalyst to synthesize di- and ... General Procedure for Triarylamine Synthesis from Diphenylamine (Table 7 ...

Bromobenzene Structure

3-anisidine Structure

~24%

N-Phenyl-m-anisidine Structure

N-Phenyl-m-anisidine

3-methoxy-N,N-diphenylaniline Structure

3-methoxy-N,N-d...

Structure

4-Chlorobiphenyl Structure

4-Chlorobiphenyl

~39%

N-Phenyl-4-biphenylamine Structure

N-Phenyl-4-biph...

N-(4-Biphenylyl)-N-phenyl-4-biphenylamine Structure

N-(4-Biphenylyl...

4-Bromobiphenyl Structure

4-Bromobiphenyl

Structure

~23%

N-Phenyl-4-biphenylamine Structure

N-Phenyl-4-biph...

N-(4-Biphenylyl)-N-phenyl-4-biphenylamine Structure

N-(4-Biphenylyl...

3,4-Dimethylbromobenzene Structure

3,4-Dimethylbro...

Structure

~58%

N,N'-Bis(3,4-dimethylphenyl) aniline Structure

N,N'-Bis(3,4-di...

3,4-Dimethyl-N-phenylaniline Structure

3,4-Dimethyl-N-...

2-Bromopyridine Structure

2-Bromopyridine

Structure

~38%

N-phenyl-N-pyridin-2-ylpyridin-2-amine Structure

N-phenyl-N-pyri...

2-Anilinopyridine Structure

2-Anilinopyridine

4,4'-Dibromobiphenyl Structure

4,4'-Dibromobiphenyl

Diphenylamine Structure

~73%

N,N,N',N'-Tetraphenylbenzidine Structure

N,N,N',N'-Tetra...

P (i-BuNCH2CH2) 3N: an effective ligand in the palladium-cat...

[Journal of Organic Chemistry, , vol. 68, # 2 p. 452 - 459]

Amination of aryl chlorides in water catalyzed by cyclopalla...

[Tetrahedron Letters, , vol. 48, # 9 p. 1619 - 1623]

Anionic N-fries rearrangement of N-carbamoyl diarylamines to...

[Organic Letters, , vol. 8, # 6 p. 1133 - 1136]

Palladium-and nickel-catalyzed aminations of Aryl imidazolyl...

[Organic Letters, , vol. 13, # 7 p. 1784 - 1786]

Improved synthesis of 2??methoxyphenothiazine

[Journal of Heterocyclic Chemistry, , vol. 49, # 2 p. 438 - 441]