Vibrational study of the dynamics of n-decylammonium chains in the perovskite-type layer compound decylammonium tetrachlorocadmate ((C10H21NH3) 2CdCl4)

L Ricard, M Rey-Lafon, C Biran

Index: Ricard, L.; Rey-Lafon, M.; Biran, C. Journal of Physical Chemistry, 1984 , vol. 88, # 23 p. 5614 - 5620

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Citation Number: 31

Abstract

Conclusion From the observed linear relation between the Knight shifts of I4N and'H, the origin of the negative shifts of'H of ammonia molecules in metal-ammonia solutions can be attributed to the indirect hyperfine interaction between the excess electrons on I4N nuclei and'H through the NH bond. The observed maximum in the curves for the relaxation rates of 14N and'H is explained by the contribution from the hyperfine interaction with the excess ...