The binuclear phthalocyanines have attracted much interest as potential catalysts for the four electron reduction of water. 1 However, little work has been carried out into their potential use as environmental sensors for heavy metals. In fact, we could not find any previous work involving the application of non-ionophore metal-free phthalocyanines in cation sensing applications. 2 We believe that the cofacial metal-free binuclear phthalocyanines, which possess an ...