Resonance Raman spectroscopic evidence for an intramolecular interaction involving the amide and dithioester groups of N-acyl glycine ethyl dithioesters

AC Storer, Y Ozaki, PR Carey

Index: Storer, A. C.; Ozaki, Y.; Carey, P. R. Canadian Journal of Chemistry, 1982 , vol. 60, p. 199 - 209

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Citation Number: 31

Abstract

The synthesis and resonance Raman spectra of several new N-acyl glycine ethyl dithioesters RC (= O) NH-CH2-C (= S) SR are reported. The resonance Raman spectra of these compounds contain at least two peaks in the" C= S stretching region" between 1050 and 1200 cm-1. The solvent, concentration, temperature, and excitation wavelength dependencies of these features have been investigated. The results obtained are ...