Recyclable Pd-Incorporated Perovskite-Titanate Catalysts Synthesized in Molten Salts for the Liquid-Phase Oxidation of Alcohols with Molecular Oxygen

…, T Hara, N Ichikuni, N Kumada, S Shimazu

Index: Adilina, Indri Badria; Hara, Takayoshi; Ichikuni, Nobuyuki; Shimazu, Shogo Journal of Molecular Catalysis A: Chemical, 2012 , vol. 361-362, p. 72 - 79

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Abstract

A series of Pd-incorporated titanate catalysts (Pd/KSTO) were synthesized by the intercalation of Pd (NO 3) 2 into layered potassium titanate (KTO), which proceeded via a cation-exchange reaction in molten salts. Perovskite phases of Pd/KSTO for catalysis were synthesized at 600° C and above, whereas a lepidocrocite-type layered titanate structure, similar to that of the parent KTO, was retained when a lower temperature of 400° C was ...