Oriented thin films of a benzodithiophene covalent organic framework

DD Medina, V Werner, F Auras, R Tautz, M Dogru…

Index: Dogru, Mirjam; Handloser, Matthias; Auras, Florian; Kunz, Thomas; Medina, Dana; Hartschuh, Achim; Knochel, Paul; Bein, Thomas Angewandte Chemie - International Edition, 2013 , vol. 52, # 10 p. 2920 - 2924 Angew. Chem., 2013 , vol. 125, # 10 p. 2992 - 2996,5

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Citation Number: 34

Abstract

A mesoporous electron-donor covalent organic framework based on a benzodithiophene core, BDT-COF, was obtained through condensation of a benzodithiophene-containing diboronic acid and hexahydroxytriphenylene (HHTP). BDT-COF is a highly porous, crystalline, and thermally stable material, which can be handled in air. Highly porous, crystalline oriented thin BDT-COF films were synthesized from solution on different ...