New synthetic route and characterisation of phosphorus and arsenic heterocyclic compounds

RM Matos, LCG de Lima, E de Souza…

Index: Matos, Robson M.; Gomes De Lima, Luiz Carlos; De Souza, Edward; Barcelos De Souza, Ana Lucia Americano; Gomes De Lima, Miriam Bernardes; Soares Raslan, Delio Phosphorus, Sulfur and Silicon and the Related Elements, 2002 , vol. 177, # 12 p. 2859 - 2870

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Citation Number: 6

Abstract

Herein we report synthetic routes for the preparation of 2-chloro-1, 3, 2-dioxarsenane 1, O, O'-bis (5, 5-dimethyl-1, 3, 2-dioxarsenane)-2, 2-dimethyl-1, 3-propanediol 3, 2-chloro-1, 3, 2- dioxaphosphorinane 4, and 2-fluoro-1, 3, 2-dioxaphosphorinane 5. The new synthetic routes described here have the advantage to be simple, very clean and to lead to the desired compounds in very good yields. Compound 2-fluoro-1, 3, 2-dioxarsenane 2 also was ...