Chemistry–A European Journal

Transition??Metal??Free One??Pot Synthesis of Biaryls from Grignard Reagents and Substituted Cyclohexanones

F Zhou, MO Simon, CJ Li

Index: Zhou, Feng; Simon, Marc-Oliver; Li, Chao-Jun Chemistry - A European Journal, 2013 , vol. 19, # 22 p. 7151 - 7155

Full Text: HTML

Citation Number: 10

Abstract

Our site uses cookies to improve your experience. You can find out more about our use of cookies in About Cookies, including instructions on how to turn off cookies if you wish to do so. By continuing to browse this site you agree to us using cookies as described in About Cookies. ... A new strategy for the construction of biaryls by a transition-metal-free process is presented. A sequence of a Grignard reaction, dehydration, and oxidative aromatization affords the desired products ...

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4-Methylcyclohexanone Structure

589-92-4

4-Methylcyclohe...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~79%

BI-P-TOLYL Structure

613-33-2

BI-P-TOLYL

Cyclohexanone Structure

108-94-1

Cyclohexanone

P-TOLYLMAGNESIUM BROMIDE Structure

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P-TOLYLMAGNESIU...

~30%

4-Phenyltoluene Structure

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4-Phenyltoluene

1-cyclohex-2-en-1-yl-4-methylbenzene Structure

112176-17-7

1-cyclohex-2-en...

Cyclohexanone Structure

108-94-1

Cyclohexanone

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~13%

1-cyclohex-2-en-1-yl-4-methylbenzene Structure

112176-17-7

1-cyclohex-2-en...

4-Iodoanisole Structure

696-62-8

4-Iodoanisole

Cyclohexanone Structure

108-94-1

Cyclohexanone

~87%

4-Methoxybiphenyl Structure

613-37-6

4-Methoxybiphenyl

Cyclohexanone Structure

108-94-1

Cyclohexanone

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~99%

4-Phenyltoluene Structure

644-08-6

4-Phenyltoluene

1-cyclohex-2-en-1-yl-4-methylbenzene Structure

112176-17-7

1-cyclohex-2-en...

~73%

4-Phenyltoluene Structure

644-08-6

4-Phenyltoluene

4-Methylcyclohexanone Structure

589-92-4

4-Methylcyclohe...

phenylmagnesium bromide Structure

100-58-3

phenylmagnesium...

~77%

4-Phenyltoluene Structure

644-08-6

4-Phenyltoluene

2-Methylcyclohexanone Structure

583-60-8

2-Methylcyclohe...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~33%

24DIMETHYLBIPHENYL Structure

611-61-0

24DIMETHYLBIPHENYL

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

UNII:255L4HTY2B Structure

591-24-2

UNII:255L4HTY2B

~76%

3,4'-dimethyl-1,1'-biphenyl Structure

7383-90-6

3,4'-dimethyl-1...

iodoanisole Structure

529-28-2

iodoanisole

Cyclohexanone Structure

108-94-1

Cyclohexanone

~92%

1,1'-Biphenyl,2-methoxy- Structure

86-26-0

1,1'-Biphenyl,2...

4-Phenylcyclohexanone Structure

4894-75-1

4-Phenylcyclohe...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~10%

1-methyl-4-(4-phenylphenyl)benzene Structure

28952-41-2

1-methyl-4-(4-p...

1-Iodonaphthalene Structure

90-14-2

1-Iodonaphthalene

Cyclohexanone Structure

108-94-1

Cyclohexanone

~60%

1-PHENYLNAPHTHALENE Structure

605-02-7

1-PHENYLNAPHTHALENE

1-Bromo-4-iodobenzene Structure

589-87-7

1-Bromo-4-iodob...

Cyclohexanone Structure

108-94-1

Cyclohexanone

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4-Bromobiphenyl Structure

92-66-0

4-Bromobiphenyl

1-Iodonaphthalene Structure

90-14-2

1-Iodonaphthalene

3,4-Dihydronaphthalen-1(2H)-one Structure

529-34-0

3,4-Dihydronaph...

~27%

binaphthyl Structure

604-53-5

binaphthyl


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